You are right - the Tesco Healthy Living Cumberland Sausages chilled (57g each) are only 1 syn each.
The syn values don't go purely based on calories. Syn values are based on calories, protein, fat, carbohydrates and the ingredients.
The 20 cals per 1 syn rule only applies to foods that do not contain any form of free food, therefore you can't really apply them to low fat foods containing meats, etc.
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